Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ2 N,O 1}copper(II)
نویسندگان
چکیده
The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical inter-molecular C-H⋯O hydrogen bonds involving the ether O atoms link the Schiff base mol-ecules into a two-dimensional network parallel to (101).
منابع مشابه
Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl-κO]iminomethyl}phenolato-κ2 N,O 1)nickel(II) dihydrate
In the title compound, [Ni(C(12)H(16)NO(5))(2)]·2H(2)O, the Ni(II) atom is coordinated by four O atoms and two N atoms from the two 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]imino-meth-yl}phenolate ligands in a distorted octa-hedral coordination geometry. O-H⋯O hydrogen bonds link the complexes and uncoordinated water mol-ecules into two-dimensional networks parallel to (001).
متن کاملBis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate
In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa-hedral geometry arising from two N,O,O'-tridentate 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]-imino-meth-yl}phenolate ligands. The Jahn-Teller distortion of the copper centre is unusally small. In the crystal structure, O-H⋯O hydrogen bonds, some of which are bifurcated, link the component s...
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The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-H⋯O and O-H⋯Cl hydrogen-bond interactions stabilize this arran...
متن کاملBis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2 N,O]copper(II)
In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each oth...
متن کاملRedetermination of bis(2-formylphenolato-κ2 O,O′)nickel(II) as bis[2-(iminomethyl)phenolato-κ2 N,O′]nickel(II)
The crystal structure of bis-(2-formyl-phenolato-κ(2)O,O')nickel(II), [Ni(C(7)H(5)O(2))(2)], a square-planar centrosymmetric complex, has been reported previously [Li & Chen (2006). Acta Cryst. E62, m1038-m1039]. However, a number of warning signs allows the assumption that the carbonyl group in the salicylaldehydate ligand of the claimed complex is incorrect. The crystal structure was therefor...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008